ENABLERS

For nanoparticulate dispersions and coatings, certain enablers must be present to achieve success: (1) effective particle preparation, (2) stabilization of the dispersed phase, (3) scaleup and control of the process, and (4) the existence of excellent analytical capabilities. The main methods or issues for each are described below.

1. Particle preparation. Wet chemical methods such as liquid phase precipitation or sol-gel methods are of high interest in particle preparation (Friedlander 1993). In the area of hybrid methods, both spray pyrolysis and flame hydrolysis are utilized. Numerous physical methods such as mechanical size reduction are also often employed.

2. Stabilization of the dispersed phase. For stabilization of the dispersed phase, it is necessary to understand how particles can be kept as distinct entities. Either a charged stabilized system or a sterically stabilized approach is required. A successful preparation for use as a dispersion should be free from agglomeration in the liquid state so as to maintain particle integrity. The dry-coated format of nanoparticles should also minimize any presence of particle aggregation

3. Scaleup and control of the process. The scaleup and control of nanoparticle processing is well described by Kear (1998). Here, the issue in achieving a high rate of production of powder is the effective pyrolysis of the gas stream containing the precursor. Issues such as scaling and reproducibility from one run of nanoparticle material or dispersions to another are all inherent in the concept of precision engineering or invariant process control.

4. Analytical capabilities. Analytical capabilities are absolutely essential for characterizing dispersions and coatings (Angstrom 1995). Particle size determinations, assay analysis, and interfacial properties are all important. Transmission electron microscopes, atomic force microscopy, nuclear magnetic resonance, and scanning tunneling microscopy are just some of the tools utilized in characterizing nanoparticle dispersions and coatings, particularly at the very small end of the nanoscale.


Published: September 1999; WTEC Hyper-Librarian